离子液体[C2O2BBTA][TFA]催化合成3,4-二氢嘧啶-2-(1H)-酮/硫酮
Synthesis of 3,4-Dihydropyrimidine-2-(1H)- Ones/Thiones Catalyzed by Ionic Liquid [C2O2BBTA][TFA]

作者: 张增鹏 , 麻 荣 , 郭 磊 , 刘晨江 :石油天然气精细化工教育部&自治区重点实验室,新疆大学理化测试中心,新疆 乌鲁木齐 ;

关键词: 离子液体催化无溶剂34-二氢嘧啶酮-2(1H)-酮/硫酮Ionic Liquids Catalysis Solvent-Free 34-Dihydropyrimidin-2(1H)-Ones/Thiones

摘要:
无溶剂条件下,阳离子为苯并三唑、阴离子为三氟乙酸根的羧基功能化离子液体作为环境友好的催化剂,高效地合成了一系列3,4-二氢嘧啶-2(1H)-酮或硫酮。此外,离子液体[C2O2BBTA][TFA]循环使用至少4次,且催化活性没有明显降低。

Abstract: Carboxyl functional ionic liquid with benzotriazole cation and trifluoroacetate anion can be used as environmental-friendly catalyst for the efficient synthesis of 3,4-dihydropyrimidin-2(1H) ones /thiones under solvent-free conditions. Moreover, the ionic liquid [C2O2BBTA][TFA] can be easily recycled and reused for at least four cycles without obvious loss of catalytic activity.

文章引用: 张增鹏 , 麻 荣 , 郭 磊 , 刘晨江 (2017) 离子液体[C2O2BBTA][TFA]催化合成3,4-二氢嘧啶-2-(1H)-酮/硫酮。 有机化学研究, 5, 78-85. doi: 10.12677/JOCR.2017.52010

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