Carbonization of Mesostructured Cellular Foams and Its Effect on the Glucose Oxidase Adsorption Performance
Abstract: The mesostructured cellular foams (MCFs) were synthesized using microemulsion templating, in which the nonionic triblock copolymer surfactant Pluronic P123 was served as template and 1,3,5-trimethylbenzene (TMB) as organic swelling agent. Then, by using mesostructured cellular foam silica as templates, furfuryl alcohol as carbon precursors, the carbon-based mesostructured cellular foam was prepared. The exterior morphologies and pore structures of the samples were characterized by Scanning Electron Microscope (SEM), Transmission Electron Microscopy (TEM) and nitrogen adsorption. It was found that mesostructured cellular foams kept its original particle size and external morphology after carbonization, and possessed the smaller windows and cell diameters and the smaller pore volumes, but had larger specific surface area. Both carbon-based and silicon-based mesocellular foams were used as the carriers for immobilization of glucose oxi-dase. The loading amounts on carbonaceous mesocellular foams were much higher than on the corresponding silicon templates. We can conclude that carbon-based mesocellular foam with smaller particle size, smaller window size and smaller pore volume had a better glucose oxidase adsorption performance. It might be served as the prospective enzyme carrier material.
文章引用: 罗大鹏 , 尹光福 , 周凤娇 (2016) MCFs的碳化对其葡萄糖氧化酶吸附性能的影响。 材料科学， 6， 189-196. doi: 10.12677/MS.2016.63024
Ramanavicius, A., Kausaite, A. and Ramanaviciene, A. (2005) Biofuel Cell Based on Direct Bioelectrocatalysis. Biosens Bioelectron, 20, 1962-1967.
Sakai, H., et al. (2009) A High-Power Glucose/Oxygen Biofuel Cell Operating under Quiescent Conditions. Energy & Environmental Science, 2, 133-138.
 康峰, 伍艳辉, 李佟茗. 生物燃料电池研究进展[J]. 电源技术, 2004, 28(11): 723-727.
Agnès, C., Reuillard, B., Goff, A.L., Holzinger, M. and Cosnier, S. (2013) A Dou-ble-Walled Carbon Nanotube-Based Glucose/H2O2 Biofuel Cell Operating under Physiological Conditions. Electro-chemistry Communications, 34, 105-108.
Yan, Y., Wei, J., Zhang, F.Q., Meng, Y., Tu, B. and Zhao, D.Y. (2008) The Pore Structure Evolution and Stability of Mesoporous Carbon FDU-15 under CO2, O2 or Water Vapor Atmospheres. Microporous and Mesoporous Materials, 113, 305-314.
Li, J., Ding, Y., Liao, X.M., Chen, X.C., Huang, Z.B., Yao, Y.D. and Pu, X.M. (2013) Amino-Functionalized Mesostructured Cellular Foams as Carriers of Glucose Oxidase. Journal of Bioscience and Bioengineering, 116, 555-561.
Zhou, F.J., Pu, X.M., Luo, D.P., Yin, G.F., Zhuang, K., Liao, X.M., et al. (2015) Glucose Oxidase Adsorption Performance of Carbonaceous Mesocellular Foams Prepared with Different Carbon Sources. Journal of Bioscience and Bioengineering, 120, 9-16.
Zhou, M., Deng, L., Wen, D., Shang, L., Jin, L.H. and Dong, S.J. (2009) Highly Ordered Mesoporous Carbons-Based Glucose/O2 Biofuel Cell. Biosensors and Bioelectronics, 24, 2904-2908.
Schmidt-Winkel, P., Lukens, Jr., W.W., Zhao, D.Y., Yang, P.D., Chmelka, B.F. and Stucky, G.D. (1999) Mesocellular Siliceous Foams with Uniformly Sized Cells and Windows. Journal of the American Chemical Society, 121, 254-255.
Lu, A.H., Schmidt, W., Spliethoff, B. and Schüth, F. (2003) Synthesis of Ordered Mesoporous Carbon with Bimodal Pore System and High Pore Volume. Advanced Materials, 15, 1602-1606.
Lee, D., Lee, J., Kim, J., Kim, J., Na, H.B. and Kim, B. (2005) Simple Fabrication of a Highly Sensitive and Fast Glucose Biosensor Using Enzymes Immobilized in Mesocellular Carbon Foam. Advanced Materials, 17, 2828-2833.
Ding, Y., et al. (2012) Rapid and High-capacity Adsorption of Glucose Oxidase on Amine-Functionalized Mesoporous Silica SBA-15 Platelets. Chemistry Letters, 41, 1512-1514.