Palladium-Catalyzed Allyl Oxime from Allyloxycarbonyl Oxime
Abstract: Oximes, which are important classes of nitrogen compounds, are ubiquitous in natural products, drugs as well as materials, and are important intermediates in organic synthesis. We have devel-oped a mild and convenient protocol for the synthesis of allyl oximes. In the presence of Pd(PPh3)4 and DCM, allyloxycarbonyl oximes successfully underwent decaboxylate reaction at room tem-perature to afford the corresponding allyl oximes in moderate good yields in eight minutes. And the possible mechanism of the reaction was discussed.
文章引用: 蔡 波 , 李文广 , 皮少锋 , 孙汉州 (2015) 钯催化烯丙基碳酸肟脱羧合成烯丙基肟。 有机化学研究， 3， 84-89. doi: 10.12677/JOCR.2015.31012
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