不同反应时间下纳米CeO2的合成与表征
Synthesis and Characterization of Nano-CeO2 under Different Reaction Time

作者: 张小伟 , 査根胜 , 汪思佳 , 包玲玲 :安徽大学物理与材料科学学院,合肥; 孟凡明 :安徽大学安徽省信息材料与器件重点实验室,合肥;

关键词: 水热法二氧化铈反应时间形貌可控Hydrothermal Synthesis CeO2 Reaction Time Controllable Morphology

摘要:
以硝酸铈为铈源,硝酸为酸性控制剂,在酸性条件下,利用水热法制备萤石型立方相球状二氧化铈。通过改变反应时间,制得了不同条件下的球形二氧化铈产品。通过X射线衍射仪(XRD),扫描电子显微镜(SEM),拉曼光谱仪(Raman),紫外可见分光光度计(JV-DRS)对产物的结构,形貌和性质进行表征和研究。结果表明,在酸性条件下,通过改变反应时间能够控制二氧化铈样品的形貌及性能。

Abstract: With cerium nitrate as the source of cerium and nitric acid as the acidic control agent, under acid condition, the fluorite cubic phase prepared by hydrothermal method globular ceria, by changing the reaction time, without changing the other reaction conditions, we have made with spherical cerium dioxide products under different conditions. Through the X-ray diffraction (XRD), scanning electron microscope (SEM), Raman spectroscopy (Raman), uv-vis spectrophotometer (JV-DRS) on product structure, morphology and properties were characterized and studied. The results showed that under acidic condition, changing reaction time can control the morphology and performance of the nano-CeO2.

文章引用: 张小伟 , 査根胜 , 汪思佳 , 包玲玲 , 孟凡明 (2014) 不同反应时间下纳米CeO2的合成与表征。 合成化学研究, 2, 56-62. doi: 10.12677/SSC.2014.23007

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