分析化学进展

Vol.2 No.4 (November 2012)

酸溶电感耦合等离子体发射光谱法同时快速测定地质样品中硅酸盐成分
Simultaneous Determination for Components of Silicate in Geological Samples by Inductively Couple Plasma-Atomic Emission Spectrometric with Acid Digestion

 

作者:

王 頔 , 汪君 , 赵建新 :核工业新疆理化分析测试中心

 

关键词:

酸溶电感耦合等离子发射光谱法(ICP-AES)硅酸盐分析地质Acid Digestion Inductively Coupleplasma-Atomic Emission Spectrometric (Icp-Aes) Silicate Analysis Geological

 

摘要:

样品用硝酸-硫酸-氢氟酸混合酸熔解,电感耦合等离子体发射光谱法同时快速测定地质样品中硅酸盐成分(Al2O3, Fe2O3(T), CaO, MgO, Na2O, P2O5, MnO and TiO2)。优化了分析谱线,选择了背景校正模式,采用背景扣除有效消除测定的干扰。以国家标准物质GBW04117-04122验证,方法精密度(RSD, n = 10) < 5%,相对误差(RE) < 6%,检出限LD0.0011%~0.125%。具有分解样品彻底完全、简单,时间短等特点。方法易于掌握,一次熔样可以同时快速测定硅酸盐各成分,满足分析方法要求,在实际生产中得到了良好的应用,适用于大批量样品分析。

The ore samples were digested with HNO3-H2SO4-HF mixed acid and the method for every compo- nents-Al2O3, Fe2O3(T), CaO, MgO, Na2O, P2O5, MnO and TiO2 of silicate in samples were directly determined by in- ductively couple plasma-atomic emission spectrometric (ICP-AES) was established. The conditions for selection of analysis lines were optimized. And the functions of background correction were also selected. The interferences were eliminated by using off peak background correction. The method provides the advantages of relative standard deviations (RSD, n = 10) < 5% and relative errors (RE) < 6% with determination limits (LD) range from 0.0011% - 0.125% by vali- dating using standard samples GBW 04117-04122. This method exhibited simplicityrapidity and completely making it suitable for multi-elemental determination. Furthermorethis proposed method has been well applied to the determina- tion in the daily work and met the requirements of national standards.

文章引用:

王 頔 , 汪君 , 赵建新 (2012) 酸溶电感耦合等离子体发射光谱法同时快速测定地质样品中硅酸盐成分。 分析化学进展, 2, 29-32. doi: 10.12677/AAC.2012.24006

 

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