纳米技术

Vol.4 No.2 (May 2014)

碳钢表面Zn掺杂Fe2O3纳米线的制备及其可见光光电化学性能
Preparation of Zn-Doped Fe2O3 Nanowires on Carbon Steels and Their Photoelectrochemical Performance under Visible Light

 

作者:

马荣伟 , 罗晶晶 , 张 南 , 邵 辰 , 范旭良 , 周小顺 , 牛振江 :先进催化材料教育部重点实验室,固体表面反应化学浙江省重点实验室,浙江师范大学物理化学研究所,金华

 

关键词:

碳钢转化膜Zn掺杂Fe2O3纳米线光电化学Carbon Steel Conversion Coating Zinc-Doped Fe2O3 Nanowires Photoelectrochemistry

 

摘要:

以碳钢在1.5 mol/L草酸 + 5.0 × 104 mol/L草酸锌溶液中浸泡90 min后形成的草酸盐转化膜为前驱体,经空气中350℃热处理2 h,在碳钢表面制备出Zn掺杂的Fe2O3纳米线氧化膜。采用X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和光电流测试对氧化膜进行了表征。结果表明:Fe2O3纳米线的直径约100 nm左右。在2.5 mol/L NaOH溶液中,氧化膜在可见光照射和零偏置电压下,显示n型半导体特征的阳极光电流。Zn掺杂的Fe2O3纳米线氧化膜具有良好的光电化学性能。

Films of Zn-doped Fe2O3 Nanowires were prepared on the surface of carbon steel using a method of thermal decomposition of oxalate conversion coatings at 350˚C in air. The coating precursors were obtained by immersing the steels in ethanol solutions of 1.5 mol/L oxalic acid with 5.0 × 10−4 mol/L zinc oxalate for 90 min. The oxide films were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM) and photocurrent measurement. The results indicate the Fe2O3 nanowires with diameter of ~100 nm. In 2.5 mol/L NaOH solution, the oxide films generated anodic photocurrents of n-type semiconductor behavior under visible light irradiation and zero bias. The Zn doped film generated larger photocurrent than the undoped film did.

文章引用:

马荣伟 , 罗晶晶 , 张 南 , 邵 辰 , 范旭良 , 周小顺 , 牛振江 (2014) 碳钢表面Zn掺杂Fe2O3纳米线的制备及其可见光光电化学性能。 纳米技术, 4, 23-30. doi: 10.12677/NAT.2014.42005

 

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